2.5 Semi-classical approximation

For high radial number n or orbital momentum l, the Wentzel–Kramers–Brilloin (WKB) method is known to provide an excellent approximation. In fact, the WKB approximation works already surprisingly well for small values of n or l. We refer here to the review of Quigg and Rosner [17], who present a detailed study of the WKB approximation for confining potentials. Let us simply recall here some basic results. In the WKB approximation, the eigenenergies En,0 of S-waves are given by

∫rc                    (      )
  ∘  ------------           3
     μ[E − V (r)]dr =   n +  4- π ,
0
(2.33)

where rc is the classical turning point, defined by V (rc) = E. This formula is exact for the harmonic oscillator. There exists a variant, appropriate for potentials which are singular at the origin, and this modified formula is exact in the Coulomb case [17]. For positive power-law potentials Brβ, Eq. (2.33) and its generalizations to orbital excitations result in a simple analytic expression (μ = B = 1) [17]

          [                           ]
           2β √ πΓ (3 + 1)     3    l  2β∕(β+2)
EWn,lKB =   --------21----β-(n + --+ --)        .
                Γ (β)          4   2
(2.34)

For the radial excitations with l = 0 in a linear potential (β = 1), one gets the results shown in Table 2.2, where a comparison is made with the exact eigenvalues.


Table 2.2: WKB and exact energies for S-wave energy levels in the potential V (r) = r




n WKB Exact



0 2.3202 2.3381
1 4.0818 4.0879
2 5.5172 5.5206
3 6.7844 6.7867
4 7.9425 7.9441
5 9.0214 9.0226
6 10.039110.0402
7 11.007711.0085
8 11.935311.9360
9 12.828112.8288




Table 2.3 shows the WKB approximation vs.compared with the exact numerical value for the leading Regge trajectory (n = 0) of the linear potential. Also shown is the variational approximation obtained from the trial wave function rl+1 exp(1 2αr2) borrowed from the harmonic oscillator, with the result

         ( 3    ) [Γ (2 + l)  1   ]3∕2
Eva0r,l =  3  --+ l   ---3---- ------    .
           2       Γ (2 + l) 3 + 2l
(2.35)


Table 2.3: WKB, exact and variational energies for the lowest Regge trajectory in the potential V (r) = r





lWKBExactVariat.




02.32022.33812.3448
13.26163.36123.3678
24.08184.24824.2544
34.82635.05095.0569
45.51725.79445.8001
56.16716.49306.4985
66.78447.15597.1612
77.37487.78947.7946
87.94258.39828.4032





The quality of the WKB approximation at large orbital momentum is good, but not impressive.