For high radial number n or orbital momentum l, the Wentzel–Kramers–Brilloin (WKB) method is known to provide an excellent approximation. In fact, the WKB approximation works already surprisingly well for small values of n or l. We refer here to the review of Quigg and Rosner [17], who present a detailed study of the WKB approximation for confining potentials. Let us simply recall here some basic results. In the WKB approximation, the eigenenergies En,0 of S-waves are given by
![]() | (2.33) |
where rc is the classical turning point, defined by V (rc) = E. This formula is exact for the harmonic oscillator. There exists a variant, appropriate for potentials which are singular at the origin, and this modified formula is exact in the Coulomb case [17]. For positive power-law potentials Brβ, Eq. (2.33) and its generalizations to orbital excitations result in a simple analytic expression (μ = B = 1) [17]
![]() | (2.34) |
For the radial excitations with l = 0 in a linear potential (β = 1), one gets the results shown in Table 2.2, where a comparison is made with the exact eigenvalues.
n | WKB | Exact |
0 | 2.3202 | 2.3381 |
1 | 4.0818 | 4.0879 |
2 | 5.5172 | 5.5206 |
3 | 6.7844 | 6.7867 |
4 | 7.9425 | 7.9441 |
5 | 9.0214 | 9.0226 |
6 | 10.0391 | 10.0402 |
7 | 11.0077 | 11.0085 |
8 | 11.9353 | 11.9360 |
9 | 12.8281 | 12.8288 |
Table 2.3 shows the WKB approximation vs.compared with the exact numerical value for the leading Regge trajectory (n = 0) of the linear potential. Also shown is the variational approximation obtained from the trial wave function rl+1 exp(−1 2αr2) borrowed from the harmonic oscillator, with the result
![]() | (2.35) |
l | WKB | Exact | Variat. |
0 | 2.3202 | 2.3381 | 2.3448 |
1 | 3.2616 | 3.3612 | 3.3678 |
2 | 4.0818 | 4.2482 | 4.2544 |
3 | 4.8263 | 5.0509 | 5.0569 |
4 | 5.5172 | 5.7944 | 5.8001 |
5 | 6.1671 | 6.4930 | 6.4985 |
6 | 6.7844 | 7.1559 | 7.1612 |
7 | 7.3748 | 7.7894 | 7.7946 |
8 | 7.9425 | 8.3982 | 8.4032 |
The quality of the WKB approximation at large orbital momentum is good, but not impressive.